>>> a = {0:'000000',1:'11111',3:'333333',4:'444444'}
>>> a.keys()
[0, 1, 3, 4]
>>> sorted(a.keys())
[0, 1, 3, 4]
>>> reversed(sorted(a.keys()))

>>> list(reversed(sorted(a.keys())))
[4, 3, 1, 0]